I'd like to hear other people's thoughts on using pH drop to estimate CO₂ levels.
I'm in a rather strange situation. First of all, I use two good-quality digital pH meters, both properly calibrated and well maintained. I've been using this type of equipment for years because, before getting into aquariums, I was (and still am) heavily involved in hydroponics.
Anyway, here's the situation:
My
fully degassed pH (water left degassing indoors for 72 hours) is
7.6. I know that degassing indoors theoretically results in a higher equilibrium CO₂ concentration than the commonly referenced 0.6 ppm achieved outdoors, but let's use that as a reference point.
With CO₂ running, the aquarium reaches a pH of
5.6, giving me a
pH drop of 2.0.
Using the standard ph drop relationship and assuming 0.6 ppm CO₂ at equilibrium, that would suggest roughly
60 ppm CO₂.
However, both on this forum and in various Facebook groups, I often see people reporting pH drops of around
1.0–1.4. Some have even claimed to measure about
60 ppm CO₂ with a Hanna meter while having only a
1.4 pH drop, using water degassed outdoors.
If that were true, then extrapolating from those numbers would suggest that my tank is running at something like
240 ppm CO₂, which seems highly unlikely. My fish appear perfectly fine, and my drop checkers aren't even yellow. In fact, I have three different drop checkers in the tank, using different indicator solutions and placed in different locations, just out of curiosity.
So I'm wondering:
- Do you think the pH drop method is being misinterpreted by many hobbyists?
- Could there be something fundamentally wrong with the assumptions behind comparing pH drops between different tanks?
- Has anyone here measured dissolved CO₂ directly and compared it against pH drop calculations?
I'd really be interested to hear your thoughts on this rather confusing situation.